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Does Volcarona respawn?


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Hi,

So I was trying to complete my pokedex but when I encountered Vocarona I accidently used toxic instead of spore so what happened was that it was on red health and of course my ultra ball didn't catch it. I terminated the session and went again to the relic castle location but volcarona doesn't appear to be there anymore. Will it respawn eventually or have I basically ruined everything?.

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